Monoclinic 122-Type BaIr2Ge2 with a Channel Framework: A Structural Connection between Clathrate and Layered Compounds

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Monoclinic 122-Type BaIr2Ge2 with a Channel Framework: A Structural Connection between Clathrate and Layered Compounds

A new 122-type phase, monoclinic BaIr₂Ge₂ is successfully synthesized by arc melting; X-ray diffraction and scanning electron microscopy are used to purify the phase and determine its crystal structure. BaIr₂Ge₂ adopts a clathrate-like channel framework structure of the monoclinic BaRh₂Si₂-type, with space group P2₁/c. Structural comparisons of clathrate, ThCr₂Si₂, CaBe₂Ge₂, and BaRh₂Si2 struct...

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ژورنال

عنوان ژورنال: Materials

سال: 2017

ISSN: 1996-1944

DOI: 10.3390/ma10070818